WebJan 20, 2024 · The Burgess reagent ([methoxycarbonylsulfamoyl]triethylammonium hydroxide) has historically found utility as a dehydrating agent. Herein we show that, in the presence of dimethyl sulfoxide, the Burgess reagent efficiently and rapidly facilitates the oxidation of a broad range of primary and secondary alcohols to their corresponding … WebMay 26, 2009 · The menthyl chiral auxiliary version of the Burgess reagent provides for the synthesis of diastereomeric cis-sulfamidates from epoxides and leads to optically pure β-amino alcohol derivatives. Mechanistic insight and structural revisions of previously reported results are provided, along with a Density Functional Theory computational study. ...
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WebOct 8, 2012 · N-Oxides derived from oxycodone and O-acyloxymorphone were treated with the Burgess reagent to provide the corresponding oxazolidines in excellent yields and the entire sequence from oxymorphone to the various antagonists was reduced to three one-pot operations. N-Oxides derived from oxycodone and O-acyloxymorphone were treated with … WebBurgess Reagent TCI Chemicals (India) Pvt. Ltd. Product Document Search Printed Magazine "TCIMAIL" > TCIMAIL Back Numbers 1998 > Burgess Reagent No.97 M1279 … gregg\u0027s heating and air
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WebThe Burgess reagent ( methyl N- (triethylammoniumsulfonyl)carbamate) is a mild and selective dehydrating reagent often used in organic chemistry. [1] [2] It was developed in the laboratory of Edward M. Burgess at Georgia Tech . The Burgess reagent is used to convert secondary and tertiary alcohols with an adjacent proton into alkenes. WebSynonym (s): Burgess reagent, Methyl N- (triethylammoniosulfonyl)carbamate. Linear Formula: CH3O2CNSO2N (C2H5)3. CAS No.: 29684-56-8. Molecular Weight: 238.30. … WebBurgess reagent is a selective dehydrating reagent used in organic synthesis. It is used to convert secondary and tertiary alcohol, with an … gregg\u0027s ranch dressing ingredients